Product ID:GARLON (R) 4 HERBICIDE PC 38322
MSDS Date:01/26/1989
FSC:6840
NIIN:01-328-4042
MSDS Number: BPPHQ

DOW CHEMICAL USA

MIDLAND, MI 48674
US

Emergency Phone: 517-636-4400

Info Phone: 517-636-4400

Cage: EO044

DOW CHEMICAL USA

MIDLAND, MI 48640-6030 US

Telephone: 517-636-4400

Cage: EO044

TRICLOPYR ([3,5,6-TRICHLORO-2-PYRIDINYL]OXY) ACETIC ACID,

CAS: 64700-56-7

RTECS: 9999999ZZ

Fraction By Weight: 38.4%

OSHA PEL 4M/M3,SKIN*

KEROSENE

CAS: 8008-20-6

RTECS: OA5500000

OSHA PEL 10 MG/M3*

PPOP CLYCOL ETHER

Fraction By Weight: <5%

PROPRIETARY INGREDIENTS

LD50 LC50 Mixture:ORAL LD50RAT:MALE 1581/FEMALE 1338 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SLIGHT TEMPORARY IRRITATION.
SKIN: PROLONGED/REPEATED: IRRITATION. PROLONGED/FREQUENT: ALLERGIC
REACTIONS. ABSORPTION: REPEATED EXPOSURE: HARMFUL. INGESTION: LARGE
AMOUNTS: INJURY. ASPIRATION (LI Q ENTERS LUNGS) MAY CAUSE LUNG
DAMAGE/DEATH (CHEMICAL PNEUMONIA). INHAL: UPPER RESP IRRIT, CENTRAL
NERV SYSTEM EFFECTS #
Explanation of Carcinogenicity:DID NOT CAUSE CANCER IN LONG-TERM ANIMAL
STUDIES. LD50 DERMAL RABBITS: >2,000 MG/KG.
Effects of Overexposure:# SYSTEMIC (TARGET ORGAN) EFFECTS: REPEATED
OVEREXPOSURE: LIVER, KIDNEY, BLOOD EFFECTS. TERATOLOGY (BIRTH
DEFECTS): UNLIKELY. EXPOSURES HAVING NO EFFECT ON MOTHER SHOULD
HAVE NO EFFECT ON FETUS. DID N OT CAUSE BIRTH DEFECTS IN ANIMALS.
EFFECTS WERE SEEN ONLY IN FETUS ONLY AT DOSES WHICH CAUSED TOXIC
EFFECTS TO MOTHER.

First Aid:EYES: IRRIGATE IMMEDIATELY W/WATER FOR AT LEAST 5 MINUTES.
SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTON: DO NOT INDUCE
VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCY FACILITY
IMMEDIAT ELY. INHALATION: REMOVE TO FRESH AIR IFEFFECTS OCCUR.
CONSULT A PHYSICIAN. NOTE TO DR: DECISION TO INDUCE VOMIT MADE BY
DR. WEIGH DANGER FROM LUNG ASPIRATION W/TOXICITY. NO SPECIFIC
ANTIDOTE. ##

Flash Point Method:TCC
Flash Point:147F,64C
Extinguishing Media:WATER FOG, FOAM, CO2, AND DRY CHEMICAL
Fire Fighting Procedures:USE POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:COMBUSTIBLE.

Spill Release Procedures:DIKE LARGE SPILLS. KEEP OUT OF STREAMS AND
DOMESTIC WATER SUPPLIES. ABOSRB SMALL SPILLS IN INERT MATERIAL SUCH
AS SAND.

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT
USE NEAR HEAT OR OPEN FLAME. AVOID CONTACT WITH EYES, SKIN OR
CLOTHING.
Other Precautions:DO NOT SHIP OR STORE WITH FOOD, FEEDS, DRUGS, OR
CLOTHING. DO NOT CONTAMINATE WATER, FOOD, FEED BY STORAGE OR
DISPOSAL.

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
CERTAIN OPERATIONS, USE AN APPROVED AIR-PURIFYING RESPIRATOR.
Ventilation:PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves:IMPERVIOUS GLOVES (PROLONGED/FREQUENT)
Eye Protection:USE SAFETY GLASSES.
Other Protective Equipment:FOR BRIEF CONTACT, NO PRECAUTION OTHER THAN
CLEAN BODY-COVERING CLOTHING SHOULD BE NEEDED.
Work Hygienic Practices:DOW INDUSTRIAL HYGIENE GUIDE IS 4 MG/M3 (SKIN)
FOR TRICHLOPYR. DOW INDUSTRIAL HYGIENE GUIDE IS 10 MG/M3 FOR
KEROSENE.
Supplemental Safety and Health
## SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN
RESPONSE TO REACTIONS OF THE PATIENT. REPEATED EXCESSIVE EXPOSURE
MAY AGGRAVATE PREEXISTING LIVER AND KIDNEY DISEASE.

Boiling Pt:B.P. Text:>302F,>150C
Vapor Pres:[email protected]*
Vapor Density:>1
Spec Gravity:1.08
Evaporation Rate & Reference:N/K *(KEROSENE)
Solubility in Water:EMULSIFIES
Appearance and Odor:AMBER LIQUID.

OXIDIZING MATERIAL
Stability Condition to Avoid:COMBUSTIBLE. AVOID SOURCES OF IGNITION IF
TEMPERATURE IS NEAR OR ABOVE FLASH POINT.
Hazardous Decomposition Products:NITROGEN OXIDES, HYDROGEN CHLORIDE,
AND PHOSGENE MAY RESULT UNDER FIRE CONDITIONS.

Waste Disposal Methods:IN CASE OF LARGE SPILLS, CONTACT THE DOW
CHEMICAL COMPANY. BURY CLEAN-UP MATERIALS FROM SMALL SPILLS IN AN
APPROVED LANDFILL IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.